The Presure Vacumn Breaker or PFB valve is located on the irregation system supply line, ussually located on the side of the house near the irrigation zone valve box.
This valve is required by city code to prevent backflow of water into the house water supply line.
On the top is a plastic cover, this should be checked often during cold weather. If the cap is cracked, it's a sign that, at one point the valve had froze. If there is a severe enough freeze in the line the cap will break and the valve will release water. If this happens, it is very costly to replace, it ussually requires a plumber.